脱氢
氢气储存
催化作用
氢
球磨机
材料科学
化学工程
氢化镁
兴奋剂
氢燃料
储能
解吸
无机化学
化学
物理化学
冶金
有机化学
热力学
吸附
物理
工程类
功率(物理)
光电子学
作者
Liuting Zhang,Liang‐Wen Ji,Zhendong Yao,Nianhua Yan,Ze Sun,Xinglin Yang,Xinqiao Zhu,Shuanglin Hu,Lixin Chen
标识
DOI:10.1016/j.ijhydene.2019.06.065
摘要
Reversible hydrogen storage in MgH2 under mild conditions is a promising way for the realization of “Hydrogen Economy”, in which the development of cheap and highly efficient catalysts is the major challenge. Herein, A two-dimensional layered Fe is prepared via a facile wet-chemical ball milling method and has been confirmed to greatly enhance the hydrogen storage performance of MgH2. Minor addition of 5 wt% Fe nanosheets to MgH2 decreases the onset desorption temperature to 182.1 °C and enables a quick release of 5.44 wt% H2 within 10 min at 300 °C. Besides, the dehydrogenated sample takes up 6 wt% H2 in 10 min under a hydrogen pressure of 3.2 MPa at 200 °C. With the doping of Fe nanosheets, the apparent activation energy of the dehydrogenation reaction for MgH2 is reduced to 40.7 ± 1.0 kJ mol−1. Further ab initio calculations reveal that the presence of Fe extends the Mg–H bond length and reduces its bond strength. We believe that this work would shed light on designing plain metal for catalysis in the area of hydrogen storage and other energy-related issues.
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