电化学
电解质
氨
电化学电池
无机化学
介电谱
材料科学
化学
分析化学(期刊)
快离子导体
化学工程
离子电导率
循环伏安法
质子导体
电极
物理化学
有机化学
工程类
作者
E. Vasileiou,Vasileios Kyriakou,I. Garagounis,Anastasios Vourros,A. Manerbino,W. Grover Coors,Michael Stoukides
标识
DOI:10.1016/j.ssi.2015.12.022
摘要
The electrochemical synthesis of ammonia from N2 and H+ ions was studied over a Ni–BZCY72 cermet, with and without H2 in the gas phase. The effect of temperature, cathode chamber feed composition and applied voltage was explored in detail. Without H2 in the cathode chamber, the highest rate was 1.7 × 10− 9 mol/s·cm2 at 620 °C. When H2 was present in the gas phase, ammonia was synthesized electrochemically at much higher rates and Faradaic efficiencies. The maximum net electrochemical synthesis rate of 4.1 × 10− 9 mol/s·cm2 was obtained with ΡΗ2/ΡΝ2 = 1 at 620 °C, corresponding to a 140% enhancement of the open circuit rate at the cost of electrical energy. In both cases these high rates were accompanied by a low Faradaic efficiency, pointing to the need for catalyst improvement.
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