Green synthesis of Kenaf-based activated carbons with excellent rate capability and cycle-life via hydrothermal-co-activation process for high-performance capacitive energy storage

The invention of high-performance electrode materials through a simple and green approach is always important for energy storage applications. Herein, we have prepared highly porous activated carbons (ACs) from biomass kenaf (KF) by hydrothermal and steam activation methods. A number of optimization experiments, such as hydrothermal pre-treatment (100, 150 and 200 oC), steam activation temperature (600, 700, 800, and 900 oC) and time of steam flow (15, 30, 60 and 90 min) were performed to control the specific surface area, micro- and/or meso-pores, total pore volume for an excellent electrochemical performance. The as-obtained porous ACs exhibited a high specific surface area (~1733 m2/g) with high total pore volume (~0.916 cm3/g) and high mesopore volume (~28.4%), which are beneficial for the excellent double layer formation over the surface of activated electrode and also provide transport channel for an effective diffusion of electrolyte ions. The as-derived ACs were used as electrode materials for the fabrication of symmetric supercapacitor device in 6 M KOH. The fabricated device exhibited a high energy density of 4.86 Wh kg-1 at power density of 2500 W kg-1 with outstanding stability (~96.3%) over 10,000 charge-discharge cycles.