Morphological Tuning of Covalent Organic Framework Single Crystals

The synthesis of high-quality single-crystal covalent organic frameworks (COFs) presents significant challenges, particularly in achieving precise control over their morphologies. Herein, we present a straightforward strategy to fine-tune the morphology of COF single crystals. Using rigid triptycene derivatives as the core building blocks and varying the amounts of aniline modulators, we successfully synthesized a series of high-quality COF single crystals with different aspect ratios and well-defined facets, JUC-663-X (X = 30 to 135, the equivalent of aniline). Their structures were characterized using PXRD, TEM, and N