香兰素
肟
化学
羟胺
催化作用
糠醛
有机化学
丁香醛
氨
作者
Wanping Zheng,Shanshan Feng,Changwei Hu
标识
DOI:10.1002/cssc.202301364
摘要
Abstract Oxime chemicals are the building blocks of many anticancer drugs and widely used in industry and laboratory. A simple but robust hierarchically porous zeolite (HTS‐1) catalyst was prepared by hydrothermal methods and used for the preparation of vanillin oxime from vanillin in NH 3 ⋅ H 2 O/DIO (v/v 1/10) system. The results of the catalyst characterization showed that the larger pore size and more framework Ti were conducive to promote the transformation of the substrates. The conversion of vanillin and the yield of vanillin oxime were both higher than 99 % under optimized reaction conditions. It was found that the reaction proceeded by oxidation of NH 3 to hydroxylamine (NH 2 OH), and oximation of hydroxylamine with vanillin to obtain vanillin oxime, where the rate‐controlling step was the hydroxylamine formation, and the apparent activation energy was 26.22 kJ/mol. The corresponding oximation products could also be obtained by extending this method to other compounds derived from lignin. Furthermore, the catalytic system was used directly to the conversion of birch biomass to obtain oxime products such as vanillin oxime, syringaldehyde oxime, and furfural oxime etc. This work might give insights into the sustainable production of N‐containing high‐value products from lignocellulose.
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