Conjugated ladder polymers: Advances from syntheses to applications

共轭体系 聚合物 纳米技术 高分子科学 材料科学 复合材料
作者
James Shao-Jiun Yang,Lei Fang
出处
期刊:Chem [Elsevier BV]
卷期号:10 (6): 1668-1724 被引量:14
标识
DOI:10.1016/j.chempr.2024.04.002
摘要

The bigger pictureOver the past century, the vast majority of polymers synthesized and studied by humanity were single stranded. Research on multi-stranded polymers, such as ladder polymers, presents a compelling challenge for chemists. Although ladder polymer chemistry is nascent compared with that of traditional polymers, it has seen significant advancements in recent decades. Among these multi-stranded polymers, conjugated ladder polymers (CLPs) are particularly noteworthy, thanks to their distinct electronic structures that contribute to unique electronic, optical, and magnetic properties. These properties, along with CLPs' extraordinary stability, could address challenges in various cutting-edge application fields; e.g., bioelectronic devices, wearable electronics, and sustainable energy storage. Future research should focus on developing new sustainable synthetic methods, applying large-area processing techniques, and enhancing the integrated functions of these polymers.SummaryConjugated ladder polymers (CLPs) represent a fascinating class of macromolecules characterized by their multi-stranded, π-conjugated structures with uninterrupted fused rings forming the backbone. Their unique constitution presents synthetic challenges that extend beyond those associated with conventional conjugated polymers. The synthesis of CLPs is typically achieved through one-pot annulative ladder polymerization or a two-step process involving polymerization followed by post-polymerization cyclization. Over the past decade, numerous innovative synthetic techniques and novel CLP structures have emerged. The distinctive architectures of these CLPs endow them with exceptional properties and robustness that are often unmatched by conventional non-ladder polymers. Significant progress has been made in the application of CLPs in various domains, such as organic semiconductors, active materials in organic electrochemical transistors, and organic thermoelectric devices. Despite these advances, the field continues to face a series of chemical and engineering challenges that must be overcome to fully harness the potential of CLPs as a highly promising class of functional organic materials.Graphical abstract
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
猫猫完成签到,获得积分10
刚刚
2秒前
momo发布了新的文献求助10
3秒前
小宇子发布了新的文献求助10
3秒前
Mr兔仙森完成签到,获得积分10
4秒前
LJJ发布了新的文献求助10
5秒前
5秒前
Culto完成签到,获得积分10
6秒前
7秒前
JIE完成签到,获得积分10
7秒前
houjibofa发布了新的文献求助10
8秒前
田様应助幽默平安采纳,获得10
11秒前
可爱的函函应助刘小小123采纳,获得10
12秒前
瓣落的碎梦完成签到,获得积分0
14秒前
善学以致用应助momo采纳,获得10
15秒前
孝顺的觅风完成签到 ,获得积分10
15秒前
17秒前
刘小小123发布了新的文献求助10
20秒前
健壮的面包完成签到,获得积分10
20秒前
23秒前
孙燕应助科研界的恩希玛采纳,获得20
26秒前
27秒前
迷茫的一代完成签到,获得积分10
29秒前
量子星尘发布了新的文献求助10
29秒前
xingxingwang完成签到,获得积分10
30秒前
春来发布了新的文献求助30
31秒前
32秒前
32秒前
刘小小123完成签到,获得积分20
32秒前
xzy完成签到 ,获得积分10
33秒前
搜集达人应助无情向梦采纳,获得10
35秒前
阿伟1999发布了新的文献求助50
37秒前
momo发布了新的文献求助10
38秒前
li完成签到,获得积分10
39秒前
如此发布了新的文献求助10
41秒前
42秒前
赵静1234567890完成签到,获得积分10
42秒前
xxxllllll发布了新的文献求助10
46秒前
科研通AI2S应助科研通管家采纳,获得10
46秒前
Owen应助科研通管家采纳,获得10
46秒前
高分求助中
A new approach to the extrapolation of accelerated life test data 1000
ACSM’s Guidelines for Exercise Testing and Prescription, 12th edition 500
‘Unruly’ Children: Historical Fieldnotes and Learning Morality in a Taiwan Village (New Departures in Anthropology) 400
Indomethacinのヒトにおける経皮吸収 400
Phylogenetic study of the order Polydesmida (Myriapoda: Diplopoda) 370
基于可调谐半导体激光吸收光谱技术泄漏气体检测系统的研究 350
Robot-supported joining of reinforcement textiles with one-sided sewing heads 320
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 3989334
求助须知:如何正确求助?哪些是违规求助? 3531428
关于积分的说明 11253936
捐赠科研通 3270119
什么是DOI,文献DOI怎么找? 1804887
邀请新用户注册赠送积分活动 882087
科研通“疑难数据库(出版商)”最低求助积分说明 809173