Organic Solar Cells Based on Non‐Fullerene Low Molecular Weight Organic Semiconductor Molecules

Abstract The development of narrow bandgap A‐D‐A‐ and ADA′DA‐type non‐fullerene small molecule acceptors (NFSMAs) along with small molecule donors (SMDs) have led to significant progress in all‐small molecule organic solar cells. Remarkable power conversion efficiencies, nearing the range of 17–18 %, have been realized. These efficiency values are on par with those achieved in OSCs based on polymeric donors. The commercial application of organic photovoltaic technology requires the design of more efficient organic conjugated small molecule donors and acceptors. In recent years the precise tuning of optoelectronic properties in small molecule donors and acceptors has attracted considerable attention and has contributed greatly to the advancement of all‐SM‐OSCs. Several reviews have been published in this field, but the focus of this review concerns the advances in research on OSCs using SMDs and NFSMAs from 2018 to the present. The review covers the progress made in binary and ternary OSCs, the effects of solid additives on the performance of all‐SM‐OSCs, and the recently developed layer‐by‐layer deposition method for these OSCs. Finally, we present our perspectives and a concise outlook on further advances in all‐SM‐OSCs for their commercial application.