非随机双液模型
碳酸二甲酯
共晶体系
化学
氯化胆碱
离子液体
异丙醇
乙二醇
萃取(化学)
活度系数
物理化学
有机化学
甲醇
催化作用
水溶液
合金
作者
Chao Sun,Jiafu Xing,Yajuan Qu,Yanli Zhang,Peizhe Cui,Yinglong Wang,Jun Gao
标识
DOI:10.1021/acs.iecr.3c01045
摘要
Deep eutectic solvents (DESs) were adopted to separate the azeotropes of dimethyl carbonate (DMC) and isopropyl alcohol (IPA). Liquid–liquid equilibrium (LLE) data plays a crucial role in designing the separation process. Three appropriate DESs (choline chloride (ChCl)-Urea, ChCl-Glycerol (Gly), ChCl-Ethylene glycol (EG)) were selected using the COMSO model. Then, the LLE data of DMC-IPA-(ChCl-Urea), DMC-IPA-(ChCl-EG), and DMC-IPA-(ChCl-Gly) were obtained through experiments at 298.15 K under 101.32 kPa, the binary interaction parameters were obtained by regressing the LLE data by the nonrandom two-liquid (NRTL) model, and the GUI-Matlab was adopted to verify the precision of the NRTL interaction parameters and the experimental data. Finally, the mechanism of formation of the combined structures (DES-IPA/DMC) was explored through ESP. To further explore the extraction capacities of the selected DESs, the extraction mechanism of three DESs was revealed. The interactions between DESs and IPA/DMC were explored through penetration distance and AIM analysis; the calculation results showed that (ChCl-EG) has the best extraction capacity, which is consistent with the experimental results. The results of experimental and theoretical calculations showed that the DES could effectively separate DMC and IPA.
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