Radium isotope assessment of submarine groundwater discharge and associated nutrient inputs in Eastern Liaodong Bay, China

海底地下水排放 海湾 营养物 环境科学 地下水 海水 盐度 水文学(农业) 海洋学 地质学 生态学 含水层 化学 生物 放射化学 岩土工程
作者
Qiaona Guo,Yue Zhao,Mengjun Li,Jinhui Liu
出处
期刊:Frontiers in Marine Science [Frontiers Media]
卷期号:9 被引量:3
标识
DOI:10.3389/fmars.2022.916109
摘要

The accurate assessment of submarine groundwater discharge (SGD) and associated nutrient fluxes plays a significant role in water resources management and ecological environment protection in the coastal area. Currently, Liaodong Bay has become one of the most polluted marine areas in China. However, the nutrient fluxes carried by the SGD and its environmental effects have not yet been thoroughly reported in eastern Liaodong Bay, China. In this study, the distribution of 224 Ra/ 223 Ra activity ratio and its influencing factors under the geochemical conditions were explored. The activity of radium was affected by the water type and the geochemical factors. The radium isotopes in seawater were positively correlated with the ratios of Mg 2+ /Na + and Ca 2+ /Na + but negatively correlated with salinity and SO 4 2− . The average apparent water age was evaluated to be 13.0 days. Furthermore, based on the radium mass balance model, the total average SGD flux was calculated to be 1.31 × 10 8 m 3 day –1 . The nutrient fluxes carried by the SGD were 7.16 × 10 7 , 1.01 × 10 6 , 1.61 × 10 7 , 0.92 × 10 6 , and 5.41 × 10 7 mol day −1 for DIN, DIP, NH 4 + , NO 2 − , and NO 3 − , respectively. The nutrient inputs through the SGD have an average DIN : DIP ratio of 70, which was able to seriously affect the ecological environment. The SGD-derived nutrient fluxes were higher than the local river input, which demonstrated that the SGD was a major source of nutrients affecting regional marine ecosystems.
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