Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O2CCF2SO2F) and N‐Fluorobenzenesulfonimide

Abstract Presented is a novel intermolecular radical trifluoromethylfluorosulfonylation of unactivated alkenes under mild reaction conditions with good functional‐group tolerance in the most atom‐economic manner by using readily available Ag(O 2 CCF 2 SO 2 F) and N ‐fluorobenzenesulfonimide (NFSI). Both the trifluoromethyl and sulfonyl groups in the products originate from Ag(O 2 CCF 2 SO 2 F).