过硫酸盐
化学
催化作用
碳化
吸附
碳纤维
污水污泥
赤铁矿
过硫酸钠
降级(电信)
热解炭
化学工程
无机化学
污水处理
核化学
材料科学
有机化学
废物管理
矿物学
热解
复合材料
工程类
复合数
电信
计算机科学
作者
Xiaopeng Wang,Lin Gu,Pin Zhou,Nanwen Zhu,Cheng-xu Li,Hong Tao,Haifeng Wen,Daofang Zhang
标识
DOI:10.1016/j.cej.2017.04.101
摘要
The evolution of oxygen-functioning groups in sewage sludge based carbon is influenced by minerals presented in the raw sludge. In this study, the FeCl3 and polyacrylamide conditioned sludge in real wastewater treatment plant and demineralized sludge were carbonized in the temperature range of 300 °C–800 °C to investigate the roles of temperature and ash components on the interactions between surface groups conversion and crystalline structure evolution. The temperature-dependent ash effect on the conversion of oxygen containing groups was found by using XPS, Boehm titration, XRD and TPR characterization. The phase transfer of hematite to magnetite promoted the formation of hydrophilic organic groups at 600 °C, which may play a significant role on carbon’s adsorptive and catalytic behavior. To gain an in-depth knowledge and understanding, the as-prepared carbon was used as heterogeneous catalyst in persulfate degradation of a model pollutant 2-Naphthol. The use of carbon obtained at 600 °C (MC600) can achieve 88.7% and 47% of 2-Naphthol and TOC removal respectively at neutral pH, far higher than that of MC prepared at 300 and 800 °C. Further research revealed a strong correlation between adsorptive and catalytic efficiency of MC and its mineral structure, surface functional groups as well as operating pH. The formed hydrophilic oxygen-containing groups at higher temperature of MC600 are responsible for 2-Naphthol retention and the hydrogen bonds in siloxane bridges can easily adsorb persulfate. The pH effect on degradation in the presence of persulfate verified the broad pH operation, which is apparently superior than conducting with traditional heterogeneous Fenton process. The quenching experiments and EPR spectrum were further used to detect the oxidative species SO4- and HO, and confirmed the catalytic role of MC.
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