化学
字体
锂(药物)
单体
聚合
聚合物
高分子化学
分析化学(期刊)
有机化学
计算机科学
医学
操作系统
内分泌学
作者
Soo-Jong Kim,Michiko Matsumoto,Kiyotaka Shigehara
标识
DOI:10.1002/(sici)1099-1409(200001/02)4:1<136::aid-jpp213>3.0.co;2-j
摘要
Improvement of electrical conductivity was attempted by polymerizing octacyanometallophthalocyanine (MPcOC; M ≡ Fe , Co ) units into one-dimensional molecular complexes. The synthetic route to MPcOC was established by reacting tetracyanobenzene with a metal(II) acetate in sulfolane. Poly(μ-pyrazine)octacyanophthalocyaninatoiron(II) and -cobalt(II) were synthesized and their doping with lithium was carried out. The Fe (II) and Co (II) octacyanophthalocyanine complexes showed good electrical conductivities of the order of 10 -8 -10 -4 S cm -1 . The electrical conductivities of the lithium-doped complexes were improved by two or three orders of magnitude in comparison with the corresponding monomeric and polymeric complexes.
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