Novel Clusters of Transition Metals and Main Group Oxides in the Alkylamine/Oxovanadium/Borate System

过渡金属 化学 乙二胺 齿合度 群(周期表) 结晶 无机化学 金属 结晶学 有机化学 催化作用
作者
Job Rijssenbeek,David J. Rose,Robert C. Haushalter,Jon Zubieta
出处
期刊:Angewandte Chemie [Wiley]
卷期号:36 (9): 1008-1010 被引量:108
标识
DOI:10.1002/anie.199710081
摘要

Angewandte Chemie International Edition in EnglishVolume 36, Issue 9 p. 1008-1010 CommunicationFull Access Novel Clusters of Transition Metals and Main Group Oxides in the Alkylamine/Oxovanadium/Borate System†‡ Job T. Rijssenbeek, Job T. Rijssenbeek NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA), Fax: Int. code +(609)951-2483Search for more papers by this authorDavid J. Rose, David J. Rose Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorDr. Robert C. Haushalter, Corresponding Author Dr. Robert C. Haushalter NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA), Fax: Int. code +(609)951-2483 Robert C. Haushalter, NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA), Fax: Int. code +(609)951-2483 Jon Zubieta, Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorProf. Jon Zubieta, Corresponding Author Prof. Jon Zubieta Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected] Robert C. Haushalter, NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA), Fax: Int. code +(609)951-2483 Jon Zubieta, Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this author Job T. Rijssenbeek, Job T. Rijssenbeek NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA), Fax: Int. code +(609)951-2483Search for more papers by this authorDavid J. Rose, David J. Rose Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorDr. Robert C. Haushalter, Corresponding Author Dr. Robert C. Haushalter NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA), Fax: Int. code +(609)951-2483 Robert C. Haushalter, NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA), Fax: Int. code +(609)951-2483 Jon Zubieta, Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorProf. Jon Zubieta, Corresponding Author Prof. Jon Zubieta Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected] Robert C. Haushalter, NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA), Fax: Int. code +(609)951-2483 Jon Zubieta, Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this author First published: May 16, 1997 https://doi.org/10.1002/anie.199710081Citations: 89 † The work at Syracuse University was supported by the U. S. National Science Foundation (grant no. 9318824). ‡ Dedicated to Professor Hans Georg von Schnering on the occasion of his 66th birthday AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Unprecedented structural and compositional features are exhibited by these large vanadium borate clusters (for example 1, see picture on the right). Facile solubilization and crystallization of transition metal oxides by these large, multidentate polyborate ligands portends a rich and diverse chemistry for transition element/polyborate clusters. en = ethylenediamine. References 1 M. I. Khan, L. M. Meyer, R. C. Haushalter, A. L. Schweitzer, J. Zubieta, J. L. Dye, Chem. Mater. 1996, 8, 43. 2 Y. Zhang, R. C. Haushalter, A. Clearfield, Inorg. Chem. 1996, 35, 4950 Y. Zhang, C. J. O'Connor, A. Clearfield, R. C. Haushaiter, Chem. Mater. 1996, 8, 155. 3 Y. Zhang, J. R. D. DeBord, C. J. O'Connor, R. C. Haushalter, A. Clearfield, J. Zubieta, Angew. Chem. 1996, 108, 1067; Angew. Chem. Int. Ed. Engl. 1996, 35, 989. 4 Y. Zhang, L. Meyer, R. C. Haushalter, J. Zubieta, Inorg. Chim. Acta, in press. 5 D. Hagrman, C. Zubieta, R. C. Haushalter, J. Zubieta, Angew. Chem. 1997, 109, 904; Angew. Chem. Intl. Ed. Engl. 1997, 36, 873. 6 J. DeBord, Y.-J. Lu, C. J. Warren, R. C. Haushalter, J. Zubieta, Chem. Commun. submitted. 7 M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34. 8 G. Huan, A. J. Jacobson, V. W. Day, Angew. Chem. 1991, 103, 426; Angew. Chem. Int. Ed. Engl. 1991, 30, 422. 9 P. C. Burns, J. D. Grice, F. C. Hawthorne, Can. Mineral. 1995, 33, 1131, and references therein. 10 P. D. Thompson, D. A. Keszler, Chem. Mater. 1994, 6, 2005; J. R. Cox, D. A. Keszler, J. Huang, Chem. Mater. 1994, 6, 2008; H. Behm, Acta Cryslallogr. Sect. C 1985, 41, 642; H. Behm, Acta Cryslallogr. Sect. C 1983, 39, 20. 11 C. L. Christ, J. R. Clark, Phys. Chem. Minerals 1977, 2, 59; G. Heller, J. Pickardt, Z. Naturforsch. B 1985, 40, 462; W. T. A. Harrison, T. E. Gier, G. D. Stucky, Angew. Chem. 1993, 105, 788; Angew. Chem. Int. Ed. Engl. 1993, 32, 724. 12 C. J. Warren, J. T. Rijssenbeek, D. J. Rose, R. C. Haushalter, J. Zubieta, Chem. Commun. submitted. 13 Crystal data for 1 [14b]: triclinic, P1, a = 12.48110(10), b = 13.9567(2), c = 21.8689(2) Å, α = 97.3211(10), β = 98.4310(2), γ = 114.1520(1)°, Z = 2, T = 20°C, ρcalcd = 2.182gcm−3; 9610 reflections with I > 2σ(I) and 927 parameters, R = 0.0617. 14(a) Crystal data for 2: monoclinic, C2/c, a = 22.4213(5), b = 15.3560(3), c = 22.0391(5) Å, β = 106.7920(1)°, Z = 4 T = 20°C, ρcalcd, = 2.067 gcm−3, 5195 reflections with I > 2σ(I) and 479 parameters, R = 0.0625. (b) Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Germany), on quoting the depository numbers CSD-406 454 (1) and CSD-406455. 15 I. D. Brown, K. K. Wu, Acta Cryslallogr. Sect. B 1976, 32, 1957. 16 W. A. Gale in Boron, Metallo-Boron Compounds, and Boranes (Ed.: M. Adams), Wiley, New York, 1964, p. 1. Citing Literature Volume36, Issue9May 16, 1997Pages 1008-1010 ReferencesRelatedInformation
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