Ba2WO3F4 crystallizes in acentric monoclinic symmetry, space group Ia with a = 9.281(2), b = 9.361(2), c = 7.183(1) Å and β = 92.48(2)o. It exhibits broad band fluorescent emission peaking at 475 nm both under UV and x-ray excitation. The structure and luminescence are described.
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