材料科学
固化(化学)
复合材料
环氧树脂
差示扫描量热法
活化能
复合数
等温过程
反应级数
动力学
热力学
反应速率常数
化学
量子力学
物理
有机化学
作者
Lvtao Zhu,Zhenxing Wang,Mahfuz Bin Rahman,Wei Shen,Chengyan Zhu
出处
期刊:Materials
[Multidisciplinary Digital Publishing Institute]
日期:2021-08-19
卷期号:14 (16): 4673-4673
被引量:17
摘要
The curing kinetics can influence the final macroscopic properties, particularly the three-point bending of the fiber-reinforced composite materials. In this research, the curing kinetics of commercially available glass fiber/epoxy resin prepregs were studied by non-isothermal differential scanning calorimetry (DSC). The curing kinetic parameters were obtained by fitting and the apparent activation energy Ea of the prepreg, the pre-exponent factor, and the reaction order value obtained. A phenomenological nth-order curing reaction kinetic model was established according to Kissinger equation and Crane equation. Furthermore, the optimal curing temperature of the prepregs was obtained by the T-β extrapolation method. A vacuum hot pressing technique was applied to prepare composite laminates. The pre-curing, curing, and post-curing temperatures were 116, 130, and 153 °C respectively. In addition, three-point bending was used to test the specimens’ fracture behavior, and the surface morphology was analyzed. The results show that the differences in the mechanical properties of the samples are relatively small, indicating that the process settings are reasonable.
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