Occurrence and Distribution of Per- and Polyfluoroalkyl Substances in Tianjin, China: The Contribution of Emerging and Unknown Analogues

Tianjin, located in Bohai Bay, China, constitutes a relevant study area to investigate emerging per- and polyfluoroalkyl substances (PFASs) due to its high population density, clustering of chemical and aircraft industries, as well as international airports, harbors, and oil rigs. In this study, 53 anionic, zwitterionic, and cationic PFASs were monitored in river surface water, groundwater, seawater, and sediments in this area (overall n = 226). 6:2 chlorinated polyfluorinated ether sulfonic acid (Cl-PFESA), perfluorooctanoic acid, and perfluorooctane sulfonic acid were generally the predominant PFASs. 6:2 fluorotelomer sulfonamidoalkyl betaine (6:2 FTAB) was also widespread (occurrence >86%), with the highest concentration (1300 ng/L) detected at contamination hot spots impacted by wastewater effluents. The aqueous film-forming foam (AFFF)-related PFASs with sulfonamide betaine, amine oxide, amine, or quaternary ammonium moieties are also reported for the first time in river water and seawater samples. Fifteen classes of infrequently reported PFASs, including n:2 FTABs and n:2 fluorotelomer sulfonamide amines, hydrogen-substituted PFESA homologues, and p-perfluorous nonenoxybenzenesulfonate (OBS), were also identified in the water and sediment samples using suspect screening. Field-derived sediment-water distribution coefficients (K_d) of these emerging PFASs are provided for the first time, confirming that cationic and zwitterionic PFASs tend to be strongly associated with sediments.