手性(物理)
圆二色性
涡流
化学物理
分子
纳米技术
流量(数学)
材料科学
化学
分子物理学
结晶学
物理
手征对称性
机械
有机化学
量子力学
Nambu–Jona Lasinio模型
夸克
作者
Kunihiko Okano,Takashi Yamashita
出处
期刊:ChemPhysChem
[Wiley]
日期:2012-04-19
卷期号:13 (9): 2263-2271
被引量:15
标识
DOI:10.1002/cphc.201200003
摘要
Abstract A chiral molecule absorbs preferentially right‐ or left‐handed circularly polarized light in a circular dichroism (CD) measurement. Usually, the chirality of individual molecules is regarded as the origin of the CD signals. However, recently, several reports have suggested that the vortex flow of a solution of an achiral molecule gives rise to a CD signal, which is dependent on the stirring direction. This article introduces types of molecular architecture and material designs that show stir‐induced chirality. We also discuss the effects of the molecular structure and alignment in vortex flows on this phenomena, reviewing the related issues.
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