电催化剂
铱
分解水
磷化物
钴
双功能
材料科学
化学工程
镍
化学
无机化学
电化学
催化作用
电极
冶金
物理化学
光催化
生物化学
工程类
作者
Van Hien Hoa,Muthu Austeria P,Huyen Dao,Mai Mai,Do Hwan Kim
标识
DOI:10.1016/j.apcatb.2023.122467
摘要
Surface engineering and electronic modification are the two primary elements for improving the catalytic properties of electrode materials. We significantly improved the catalytic performances of interfacial-engineered Ir nanocluster-containing cobalt phosphide/phosphate heterostructured nanowires on nickel foam (Ir-Co2P/Co2P2O7 NWs/NF) in water splitting. The optimized Ir nanocluster content of 0.05 wt% resulted in a highly efficient catalytic performance, significantly outperforming commercial IrO2 and Pt-C catalysts. The Ir0.05-Co2P/Co2P2O7 NW bifunctional electrocatalyst displayed cell potentials of 1.52, 1.60, 1.62, and 1.67 V in 1.0 M KOH and mimic, simulated, and natural seawater, respectively, at 10 mA cm−2. DFT analysis confirmed that the heterostructure enrichment in the z-oriented d-orbital facilitates strong electronic interactions between the adsorbates and surfaces. The keys were the simultaneous generation of metal phosphide/phosphate via activation of the P site on the support. Furthermore, the electrocatalyst exhibited a solar-to-hydrogen efficiency of 22.4% in solar energy-aided water splitting, indicating that it is a viable, inexpensive candidate for use in water splitting.
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