明胶
聚丙烯酰胺
海水
复合数
铀
萃取(化学)
自愈水凝胶
化学工程
化学
光热治疗
材料科学
色谱法
复合材料
高分子化学
纳米技术
冶金
有机化学
地质学
工程类
海洋学
作者
Feixiang Gao,Jianwei Bai,Huijun Yan,Shuaiyu Zheng,Shouzheng Su,Junqing Li,Chunhong Zhang,Jun Wang
标识
DOI:10.1016/j.cej.2024.149822
摘要
The development of adsorbents for highly efficient extraction of uranium from seawater is a crucial for generating nuclear energy. However, their practical application is limited because of low U/V selectivity and recovery difficulties. Herein, we developed a new magnetic photothermal composite hydrogel (Gel-Fe3O4/PAO) adsorbent to facilitate efficient recovery and selective extraction of uranium from seawater. The hydrogel exhibits excellent tensile strength and self-recovery ability owing to the double-network structure formed via the physical crosslinking of gelatin and polymerization of acrylamide (AM). Furthermore, the photothermal conversion performance of Fe3O4 nanoparticles improves the uranium selectivity of PAO and enables magnetic recovery of the hydrogel. Adsorption results show that when the Fe3O4 and gelatin contents are 1.5 wt.% and 16 wt.%, respectively, the hydrogel can be rapidly heated under light, meeting the requirements of high adsorption capacity (515.5 mg·g-1) and selectivity (Kd (U) /Kd (V) = 2.77) for uranium ions. After seven sorption-desorption cycles, the uranium adsorption capacity of the Gel-Fe3O4/PAO hydrogel remains at nearly 89 %. In simulated seawater experiments, the Gel-Fe3O4/PAO hydrogel exhibits excellent impact resistance and a high selective uranium removal rate, demonstrating its considerable potential for practical application in uranium extraction from seawater.
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