材料科学
热塑性弹性体
聚酯纤维
低聚物
缩聚物
弹性体
聚丁二酸丁二醇酯
热塑性塑料
无定形固体
极限抗拉强度
复合材料
聚合物
二醇
高分子化学
有机化学
共聚物
化学
作者
Yanyan Xu,Qinan Zhang,Zhao Wang,Liqun Zhang
出处
期刊:Polymer Testing
[Elsevier]
日期:2023-06-01
卷期号:124: 108088-108088
被引量:2
标识
DOI:10.1016/j.polymertesting.2023.108088
摘要
The development of sustainable polymers from biobased blocks is urgently desirable. In this work, a class of novel biobased thermoplastic polyester elastomers, namely poly(butylene terephthalate)-poly(1,4-butylene/2,3-butylene succinate) (PBT-PBBS) copolyesters, were designed and synthesized via melt oligomer polycondensation of common PBT oligomer and biobased PBBS oligomer. The obtained PBT-PBBS copolyesters exhibited desired block structure and contained a hard phase of crystallized PBT and a soft phase of amorphous PBBS. Their mechanical properties could be tailored by tuning the polycondensation time or the molar ratio of PBT to PBBS. Specifically, the tensile strength and the elongation at break of these copolyesters could be flexibly adjusted in the range of 6–13 MPa and 240–650%, respectively. Therefore, they are expected to be widely used in the fields of elastomers, hot-melt adhesives, and toughening modifiers.
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