Cation‐π Interactions Based Conductive Hydrogels with Slide‐Ring Structure Toward Super Long‐Time in‐air/Underwater Linear Sensing and Communication

Abstract Conductive hydrogels (CHs) are attracted more attention in the flexible wearable sensors field, however, how to stably apply CHs underwater is still a big challenge. In order to achieve the usage of CHs in aquatic environments, the integrated properties such as water retention ability, resistance to swelling, toughness, adhesiveness, linear GF sensing, and long‐term usage are necessary to consider, but rarely reported in the previous reports. This paper proposes CHs prepared using cationic and aromatic monomers along with polyrotaxanes‐based crosslinkers. Due to the intermolecular cation‐π interactions and topological slide‐ring‐based polyrotaxanes, the CHs exhibit good mechanical performance, adhesive nature, and anti‐swelling properties. The presence of slide‐ring‐based topological architecture effectively mitigates stress concentration. Additionally, the encapsulation of PA allows CHs to maintain functionality even after 240 days of direct placement at room temperature. Notably, the designed CHs exhibit linear sensitivity in detecting land/underwater human motions, and serve as Morse code signal transmitters for information transmission. Thus, the designed CHs may have broad applications in the underwater wearable sensors field.