Low-temperature photoluminescence and Raman study of monolayer WSe2 for photocarrier dynamics and thermal conductivity

Low-temperature PL analysis reveals an intriguing temperature-dependent emission pattern in WSe2: excitonic dominance above the 150 K Debye temperature, a balance between excitonic and trionic emissions at 150 K, and trionic dominance below this threshold. At lower temperatures, both excitons and trions display linearly polarized emissions, with polarization increasing from 0% at 300 K to 23% (excitons) and 7% (trions) at 150 K, and 12% for trions at 90 K. Moreover, the synthesized monolayer of WSe2 exhibits high thermal conductivity (246 W m−1 K−1 for A1g and 185 W m−1 K−1 for E2g1 modes). This property is attributed to Se vacancies and defects at triangle edges, which redirect phonons, reducing scattering and enabling efficient heat transport along boundaries. The unveiling of these novel insights within the synthesized 2D WSe2 material holds significant promise for its potential applications in nano-optoelectronics. Its demonstrated efficiency in dissipating heat, coupled with improved thermal stability, suggests the possibility of employing it in future devices. This could facilitate compact designs and the miniaturization of advanced technological tools, showcasing the material's potential for practical implementation.