Novel ammonia-sensitive sodium alginate-based films containing Co-Imd microcrystals for smart packaging application

Currently, there is an urgent requirement for the fabrication of smart packaging materials that can be applied for the real-time visual monitoring of food freshness. In this research, cubic Co-MOF (Co-Imd) microcrystal with ammonia-sensitivity and antibacterial activity was manufactured and then anchored within sodium alginate (NaAlg) matrix to construct smart packaging materials. The structure, physical and functional performances of NaAlg-based films with different content of Co-Imd (0.5, 1.0 and 2.0 wt% on NaAlg basis) were then evaluated in detail. Results reveal that the incorporated Co-Imd fillers are equally anchored within the NaAlg matrix due to the generation of new hydrogen-bonding interaction, which make an obvious improvement in mechanical strength, toughness, oxygen/water barrier, and UV-blocking ability of the NaAlg film. Moreover, the constructed NaAlg/Co-Imd blend films show superior antibacterial capability, ammonia-sensitivity function as well as color stability. Ultimately, the NaAlg/Co-Imd blend films were successfully utilized for indicating the deterioration of shrimp based on noticeable color alteration, suggesting their tremendous prospects for utilization in smart active packaging. This work offers a facile and efficient method for fabricating novel ammonia-sensitive and long-term color-stable NaAlg-based film materials with improved mechanical strength, toughness, oxygen/water barrier, UV-blocking, and antibacterial performances for smart active packaging application.