All-polymer piezo-ionic-electric electronics

Abstract Piezoelectric electronics possess great potential in flexible sensing and energy harvesting applications. However, they suffer from low electromechanical performance in all-organic piezoelectric systems due to the disordered and weakly-polarized interfaces. Here, we demonstrated an all-polymer piezo-ionic-electric electronics with PVDF/Nafion/PVDF (polyvinylidene difluoride) sandwich structure and regularized ion-electron interfaces. The piezoelectric effect and piezoionic effect mutually couple based on such ion-electron interfaces, endowing this electronics with the unique piezo-ionic-electric working mechanism. Further, owing to the massive interfacial accumulation of ion and electron charges, the electronics obtains a remarkable force-electric coupling enhancement. Experiments show that the electronics presents a high d 33 of ~80.70 pC N −1 , a pressure sensitivity of 51.50 mV kPa −1 and a maximum peak power of 34.66 mW m −2 . It is applicable to be a transducer to light LEDs, and a sensor to detect weak physiological signals or mechanical vibration. This work shows the piezo-ionic-electric electronics as a paradigm of highly-optimized all-polymer piezo-generators.