Highly Stable Metal‐Free Long‐Persistent Luminescent Copolymer for Low Flicker AC‐LEDs

Abstract Organic room‐temperature long‐persistent luminescent materials are promising light‐emitting materials for encryption, architectural decoration, organic solar cells, and biomedical applications. However, their unstable structures and thermal‐ and humidity‐induced emission quenching have greatly limited their utility and reliability. Here, we report a metal‐free nonconjugated copolymer that possesses stable photoluminescence at both high temperature and humidity. The room‐temperature long‐persistent luminescence (LPL) of this copolymer lasts for more than 15 s and can be recovered in high humidity conditions by heating to remove moisture. Copolymer LPL can be achieved with various excitation wavelengths, ranging from ultraviolet to near‐infrared, and the LPL color can be adjusted accordingly. The high initial LPL intensity and ultrafast filling time of the copolymer makes it suitable for low flicker alternating current‐driven light‐emitting diodes (AC‐LEDs).