Facile fabrication of polylactic acid/polyethylene glycol micro-nano fabrics with aligned fibrous roughness for enhancing liquid anisotropic wetting performance via double-stage drafting melt blowing process

材料科学 接触角 润湿 聚乳酸 复合材料 表面粗糙度 纳米- 表面光洁度 制作 乙二醇 聚对苯二甲酸乙二醇酯 化学工程 聚合物 替代医学 病理 工程类 医学
作者
Heng Zhang,Qi Zhen,Zhiyuan Liu,Jingqiang Cui,Xiaoming Qian
出处
期刊:Colloids and Surfaces A: Physicochemical and Engineering Aspects [Elsevier]
卷期号:648: 129174-129174 被引量:11
标识
DOI:10.1016/j.colsurfa.2022.129174
摘要

The liquid anisotropic wetting properties have garnered considerable interest due to the rapidly rising usage of functional micro-nano fabrics in sanitary product applications. However, designing and preparing such materials in a manner that is easy, safe, and vast in a large scale remains a problematic issue. In this work, a poly (lactic acid) / poly (ethylene glycol) (PLA/PEG) micro-nano fabric with aligned fibrous roughness inspired by bamboo leaves was designed and prepared via a simple double-stage drafting melt blowing process. The results indicate that aligned fibrous roughness and homogenized fiber diameters ranging from 4.4 to 2.7 µm were successfully tailed by adjusting the drafting ratios from 1.0 to 3.0. Additionally, benefiting from the aligned fibrous roughness, the PLA/PEG micro-nano fabric demonstrated excellent anisotropic wetting performance, evidenced by a clear contrast between parallel static water contact angles (θ//) and perpendicular (θ⊥) to the longitudinal direction, as well as remarkable contact angle hysteresis. Additionally, the samples had a significant aspect ratio of 3.16. As a result, this PLA/PEG micro-nano fabric may be an alternative for medical and health applications such as medical dressings and meshes.

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