Overview of the development of slippery surfaces: Lubricants from presence to absence

The superhydrophobic surfaces inspired by the lotus have excellent performances and are known for their low contact angle hysteresis and smooth surfaces. However, there are still some problems, such as the unstable structure, poor durability, high product cost and so on that need to be improved. Those issues can be avoided via liquid-infused surfaces(LIS), which are inspired by Nepenthes and consist of a mico-nano structured substrate and a smooth continuous atomic-grade lubricant. Compared with superhydrophobic surfaces, LIS not only achieves the same hydrophobic properties but also has smaller contact angle hysteresis, smoother surface, more stable structure and lower preparation cost. Although the existence of a lubricant layer improves the performance of the material, it also leaves a hidden danger, which is easy to lose and leads to the deterioration of the durability of the material. Therefore, the lubricant-free slipper materials have attracted more and more attention in recent years due to their low volatility, good durability and excellent lubrication performance. In this review, the types of LIS lubricants and their physicochemical properties were summarized at the beginning and then the applications of LIS in various fields were introduced. At the end of this paper, some solid lubricants and their applications were described, and the future development prospects of LIS lubricants also were expected.