The reaction of metallic potassium with lithium chloride was studied for the effects of time, temperature, and concentration on the yield and purity of metallic lithium. For temperatures above 750/sup 0/C the yields were in the range of 51 to 68% with purities of 84 to 96 wt %. Essentially all of the impurity was unreacted potassium which should be easily removed. A comparison of chemical potentials obtained from the literature indicated that other reactants exist which should produce lithium in higher yields.