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Catalysis of the reaction of benzoic acid with aniline by phosphorus compounds
磷化合物对苯甲酸与苯胺反应的催化
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Catalysis of the reaction of benzoic acid with aniline by phosphorus compounds 磷化合物催化苯甲酸与苯胺反应 By: Shteinberg, L. Ya.; Boiko, V. D.; Kondratov, S. A.; Shein, S. M.; Shteinberg, Ya. B. 作者： Shteinberg， L. Ya.; 博伊科，V. D.; 康德拉托夫，SA; Shein， SM; 施坦伯格，Ya. B. Zhurnal Organicheskoi Khimii (1992), 28(5), 1034-8 | Language: Russian, Database: CAplus Zhurnal Organicheskoi Khimii （1992）， 28（5）， 1034-8 |语言：俄语，数据库：CAplus Catalytic activity for amidation of PhCO2H with PhNH2 decreased in the series (EtO)2HP(O) > H3PO3 > PCl3, PBr3, MeC(OH)(PO3H2)2, (PhN:PNHPh)2 > H3PO3 (aqueous), (HPO2)n. P(III) compounds were the most active, and catalytic activity was not associated with the presence of a P-halogen bond. The catalytic mechanism was discussed. |
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