路易斯酸
选择性
光催化
碳氢化合物
铈
催化作用
兴奋剂
化学
光化学
氧化铈
碳纤维
材料科学
纳米技术
无机化学
化学工程
有机化学
光电子学
复合数
工程类
复合材料
作者
Xinying Yan,Bo Gao,Xiaoli Zheng,Mingjie Cheng,Nan Zhou,Xueqi Liu,Lina Du,Fei Yuan,Jing Wang,Xiaomin Cui,Gaoxiang Zhang,Weiqiang Kong,Qun Xu
标识
DOI:10.1016/j.apcatb.2023.123484
摘要
Photocatalytic conversion of CO2 into high valuable fuels has attracted great interest, especially for the multi-carbon products. We design and synthesize a cerium oxide (CeO2) photocatalyst with cooperatively tailored N-doping and surface frustrated Lewis pairs (FLPs), wherein the FLPs are constructed by Lewis acidic coordinatively unsaturated Ce3+ species and the adjacent Lewis basic Ce-OH groups. The synergistic effects of the FLPs and N-doping cooperatively promote the light absorption, CO2 bonding and activation, multiple proton-electron transfer processes and C-C coupling reactions, thereby improving the productivity and selectivity of photoreduction of CO2 to high-value hydrocarbons. The finely surface engineered CeO2 photocatalysts achieve 86.86% selectivity of C1 (CO, CH4) and C2 (C2H4 and C2H2) hydrocarbon products, and the selectivity for the C2 products reaches to 41.07%. It proves that the ceria catalyst is promising toward practical production of high-value multicarbon fuels using solar energy.
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