化学
电解
试剂
电化学
序列(生物学)
酮
化学计量学
组合化学
有机化学
药物化学
生物化学
电极
电解质
物理化学
作者
Ji-Hoon Jang,Dae Young Kim
标识
DOI:10.1002/ajoc.202200531
摘要
Abstract The electrochemical N ‐centered radical addition/semipinacol rearrangement sequence of alkenyl cyclobutanols with sulfonimides is described. This transformation is an environmentally friendly approach that uses cheap and easily handled sulfonimides as N ‐centered radical sources and successfully avoiding the use of stoichiometric amounts of external redox reagents. The β‐amino cyclic ketone derivatives could be synthesized in moderate to high yields from alkenyl cyclobutanol derivatives under mild constant current electrolysis conditions.
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