Adsorption characteristics of antibiotics on microplastics: The effect of surface contamination with an anionic surfactant

吸附 微塑料 化学 肺表面活性物质 土霉素 污染物 化学工程 环境化学 有机化学 抗生素 生物化学 工程类
作者
Xiangdong Xue,Shuchen Hong,Ruotong Cheng,Hong Li,Libo Qiu,Chengran Fang
出处
期刊:Chemosphere [Elsevier]
卷期号:307: 136195-136195 被引量:14
标识
DOI:10.1016/j.chemosphere.2022.136195
摘要

Microplastics and antibiotics are common, typical pollutants, and they can cause compound pollution where they coexist in the environment. Surfactants in the environment can change the interface characteristics of pollutants, and then drive the change of environmental behavior of pollutants. In this paper, we studied the physicochemical properties of complexes of polystyrene (PS) and polyethylene (PE) contaminated with sodium dodecyl benzene sulfonate (SDBS); the complexes are referred to as SPS and SPE, respectively. Taking oxytetracycline (OTC) and norfloxacin (NOR) as representatives of broad-spectrum antibiotics, the effects of SDBS on the adsorption behavior of PS and PE were analyzed and possible mechanisms were proposed. The results showed that SDBS could effectively combine with PS and PE to enhance the surface electronegativity and reduce the Brunner-Emmett-Teller (BET) specific surface area and porosity. The crystal structure remained basically unchanged, and the surface functional groups changed slightly. SDBS greatly enhanced the saturated adsorption capacities of PS and PE for OTC and NOR, and made adsorption easier, which reduced the Gibbs free energy of the adsorption system. The adsorption behaviors of SPS and SPE for the two antibiotics were consistent with the Elovich kinetic model and Sips isothermal model. SDBS enhanced the hydrophilicity of the microplastics, which facilitated their adsorption of antibiotics dissolved in water. SDBS could directly combine with antibiotics to form a complex, further increasing the adsorption capacity of the microplastics for antibiotics. The -SO3H in SDBS could combine with oxygen-containing functional groups and -NH2 in OTC and NOR. Non-ionic covalent bonds, electrostatic interactions, and hydrophobic attraction between the alkyl chain and benzene ring also played a role in adsorption. SDBS made it possible for MPs to load more types and quantities of pollutants and change their preferential adsorption selectivity, which significantly aggravated the environmental hazards.
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