化学
对称化
产量(工程)
戒指(化学)
立体化学
组合化学
有机化学
对映选择合成
催化作用
冶金
材料科学
作者
Sengodagounder Muthusamy,Boopathy Gnanaprakasam,Eringathodi Suresh
出处
期刊:Organic Letters
[American Chemical Society]
日期:2006-04-01
卷期号:8 (9): 1913-1916
被引量:18
摘要
The desymmetrization of cyclic anhydrides is carried out using dihydroxy compounds. A mild route to synthesize fused saturated/unsaturated macrocyclic tetralactones with different ring sizes (20−34) having a wide variety of spacers is described. The structure is confirmed by the representative single-crystal X-ray analysis. The multiple reduction of unsaturated macrocyclic tetralactones is also illustrated. This method is mild, selective, and efficient and achieves high yield.
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