过电位
分形
多孔性
电流(流体)
分形维数
化学
电极
扩散
多孔介质
机械
数学分析
热力学
数学
物理
电化学
物理化学
有机化学
作者
Alex Elı́as-Zúñiga,Luis Manuel Palacios-Pineda,Isaac H Jiménez-Cedeño,Óscar Martínez-Romero,Daniel Olvera-Trejo
标识
DOI:10.1016/j.jelechem.2020.114883
摘要
This article aims to investigate the solution of the fractional Troesch's equation that models the mechanism of current generation in porous electrodes by numerical integration of its equivalent power-form representation and by deriving its approximate Taylor series solution. Simulation results compare to experimental data demonstrate that the overpotential distribution and efficiency within a porous electrode, from the bottom to the top of the bed is predicted by using Troesch's fractal overpotential diffusion equation, when the fractal parameter values are α ≥ 1.2618 for a porous electrode that follows the Hausdorff dimension, or α ≥ 1.236 for El Naschie's fractal space-time.
科研通智能强力驱动
Strongly Powered by AbleSci AI