生物合成
催化作用
化学
酶
酶催化
自然(考古学)
Diels-Alder反应
有机化学
组合化学
生物
古生物学
作者
Hideaki Oikawa,Tetsuo Tokiwano
摘要
Recent studies on enzymes catalyzing the Diels- Alder reaction. often named "Diels-Alderases", clearlydemonstrated the involvement of this synthetically useful reaction in the biosynthesis of natural products.This review covers natural Diels-Alder type cycloadducts. synthetic efforts on the chemical feasibility ofthe biosynthctic Diels - Alder reaction and a brief history of studies on Diels-Alderases. In addition,reaction mechanisms of artificial and natural Diels--Alderases are discussed.
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