Cathodic electrochemiluminescence of boron and nitrogen-codoped carbon dots for the detection of dissolved oxygen in seawater

Electrochemiluminescence (ECL) is widely used in various fields due to its high sensitivity and controllable characteristics. Carbon dots (CDs) have emerged as promising ECL emitters due to their simple synthesis, low toxicity, and excellent biocompatibility. However, the practical application of many CDs emitters is hindered by their limited luminous efficiency, often necessitating additional coreactants to enhance the ECL signal intensity. In this study, we synthesized boron and nitrogen-codoped carbon dots (BN-CDs) as ECL emitters, utilizing dissolved oxygen (DO) as the coreactant. The BN-CDs/DO system exhibited a strong cathodic ECL signal. We proposed a reaction mechanism for the BN-CDs/DO ECL system. Additionally, we developed an ECL sensor for DO detection based on this system, showing a linear correlation between ECL peak intensity and DO concentration from 0.5 to 19.8 mg/L, with a detection limit of 0.12 mg/L. It was proven reliable for DO analysis in seawater and freshwater environments. This study provides insights into the synthesis and utilization of BN-CDs, highlighting the potential of DO as an intrinsic coreactant in CDs ECL systems. Furthermore, it provides new perspectives on the detection of DO in seawater and the design of innovative DO sensors.