苯乙炔
纳米复合材料
材料科学
圆二色性
纳米技术
化学
化学工程
有机化学
立体化学
工程类
催化作用
作者
Manuel Fernández‐Míguez,Manuel Núñez‐Martínez,Esteban Suárez‐Picado,Emilio Quiñoá,Félix Freire
出处
期刊:ACS Nano
[American Chemical Society]
日期:2024-10-09
标识
DOI:10.1021/acsnano.4c08622
摘要
Dynamic macroscopically chiral nanocomposites are prepared by combining silver nanoparticles (AgNPs) and dynamic helical poly(phenylacetylene)s (PPAs) bearing pendants functionalized with amino groups. These amino groups provide the nanocomposite with the ability to disperse in water along with high stability due to the interaction between the ammonium group and the AgNP. Moreover, the equilibrium between NH3+/NH2 produces a "blinking" contact between the PPA and the AgNPs, which allows total control of the dynamic helical behavior of the polymer. The use of acidic or neutral pH allows controlling the morphology of the nanocomposite, which consists of a nanosphere that has trapped inside it a single AgNP (pH = 2) or several AgNPs (pH = 7) with ca. 30 nm of diameter. These nanocomposites combine the optical and chiroptical stimuli-responsive properties of both components, AgNPs and PPAs. Thus, the controlled aggregation of the nanocomposite produced variations in the LSPR band of the AgNPs in a reversible manner. In turn, given that the chiral coating is selective to Ba2+, the presence of this metal ion caused a helical inversion of the chiral coating of the nanocomposite detected by electronic circular dichroism. Moreover, it is possible to distinguish between three metal ions in different oxidation states, such as Ce4+, Fe3+, and Hg2+, which produce different responses of the nanocomposite when oxidizing the AgNP to Ag+.
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