Strain‐Induced Heteromorphosis Multi‐Cavity Cages: Tension‐Driven Self‐Expansion Strategy for Controllable Enhancement of Complexity in Supramolecular Assembly

Coordinative supramolecular cages with adjustable cavities have found extensive applications in various fields, but the cavity modification strategies for multi-functional structures are still challenging. Here, we present a tension-driven self-expansion strategy for construction of multi-cavity cages with high structural complexity. Under the regulation of strain-induced capping ligands, unprecedented heteromorphosis triple-cavity cages S