电催化剂
废水
催化作用
钼
阳极
碳纳米管
化学
污染
阴极
碳纤维
化学工程
材料科学
电化学
纳米技术
无机化学
电极
环境科学
有机化学
环境工程
生态学
物理化学
复合材料
复合数
工程类
生物
作者
Chencheng Dong,Zhiqiang Wang,Changchun Yang,Xiaomeng Hu,Pei Wang,Xue‐Qing Gong,Lin Lin,Xiaoyan Li
标识
DOI:10.1016/j.apcatb.2023.123060
摘要
Oxygen reduction reaction (ORR) can realize the goal of in-situ H2O2 generation. A suitable catalyst ensures a proper binding strength between the electrocatalyst and the intermediate (i.e., *OOH), thereby avoiding the 4-electron ORR process and H2O production. Herein, we demonstrate that single molybdenum (Mo) atoms/clusters doped on carbon nanotubes can effectively alter the ORR pathway to generate H2O2; meanwhile, the established sequential ORR system for H2O2 production can tandemly remove ibuprofen (IBU) and other organic contaminants from water and wastewater. The results reveal that single atomic Mo clusters preferentially acted as the active sites that are merely required to overcome 0.11 eV downhill to form *OOH. Surprisingly, this tandemly constructed ORR with in-situ generated H2O2 performed better than the in-vitro H2O2 system. These findings offer a promising solution to reduce the costs related to the production and transportation of H2O2 for various applications, including the oxidation and removal of emerging organic contaminants from water and wastewater.
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