铅酸蓄电池
电解质
电化学
硫酸
阳极
二氧化铅
化学
电池(电)
硫酸盐
硫酸钠
谷氨酸
沉积(地质)
无机化学
化学工程
材料科学
钠
电极
有机化学
氨基酸
生物
生物化学
功率(物理)
古生物学
物理化学
工程类
物理
量子力学
沉积物
作者
Zhengyang Chen,Jing Cao,Yanzhao Rao,Lijia An,Yali Yang,Shuangyan Zhou,Wu Lei
标识
DOI:10.1016/j.electacta.2023.142492
摘要
High-rate partial state of charge (HRPSoC) life and stability of lead-acid batteries are largely limited by the surface morphology of lead sulfate and the reactivity of anode plates. In this study, sodium glutamate (MSG) was introduced as an electrolyte additive for lead-acid battery to improve lead sulfate deposition process and lead sulfate crystal morphology at the interface between lead anode and sulfuric acid electrolyte, and the influence of MSG on battery performance were explored. By electrochemical tests and material characterization, it was proved that glutamic acid anion can promote the formation of uniform deposition of lead sulfate with a structure similar to stacked flakes, which make it easy to form active lead and restrain irreversible sulfate during the fast charging and discharging process.
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