钝化
弯曲
钙钛矿(结构)
耐久性
材料科学
弯曲分子几何
能量转换效率
曲率半径
钙钛矿太阳能电池
结晶
曲率
复合材料
纳米技术
光电子学
化学工程
图层(电子)
工程类
几何学
流量平均曲率
平均曲率
数学
作者
Huijing Liu,Jia Xu,Huifang Han,Chenxu Zhao,Yao Fu,Kun Lang,Pengchen Zou,Xu Pan,Xingyu Gao,Kui Zhao,Jianxi Yao
标识
DOI:10.1002/adfm.202400975
摘要
Abstract The mechanical durability and efficiency of all‐inorganic flexible perovskite solar cells (f‐PSCs) still require enhancement for practical applications. In this study, a creative debridement strategy to improve the mechanical durability and photovoltaic performance of all‐inorganic f‐PSCs by pre‐bending the flexible perovskite film and then depositing the passivation agent 2‐mercaptopyridine is proposed. The pre‐bending process induced the generation of microcracks in the perovskite film surface, and 2‐mercaptopyridine can more effectively penetrate the interior of the film through the microcracks, thereby further passivating deep surface defects. These microcracks and defects can be perfectly repaired by 2‐mercaptopyridine. Bidentate coordination sites of S and N in 2‐mercaptopyridine show stronger binding energy with surface defects. The debridement strategy effectively enhanced the crystallization of the film surface and markedly inhibited crack propagation during the film's bending process. The optimized device achieves a champion power conversion efficiency (PCE) of 14.74%. The pre‐bent and passivated all‐inorganic f‐PSC shows 104% of its initial PCE after 15 000 bending cycles at a curvature radius of 3 mm. Remarkably, even after undergoing 70 000 bending cycles at a curvature radius of 5 mm, pre‐bent, and passivated f‐PSC can retain over 93% of its initial PCE, exhibiting excellent mechanical durability.
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