In situ forming dialdehyde xanthan gum-gelatin Schiff-base hydrogels as potent controlled release fertilizers

Controlled release fertilizer (CRF) hydrogels have blossomed into promising materials in agriculture owing to the sustained release of the fertilizer and also as soil conditioner. Apart from the traditional CRF hydrogels; Schiff-base hydrogels have garnered significant thrust that release nitrogen slowly in addition to reducing the environmental pollution. Herein, we have fabricated Schiff-base CRF hydrogels composed of dialdehyde xanthan gum (DAXG) and gelatin. The formation of the hydrogels was accomplished via the simplistic in situ crosslinking reaction between the aldehyde groups of DAXG and the amino groups of gelatin. The hydrogels acquired a compact network upon increasing the DAXG content in the matrix. The phytotoxic assay on different plants indicated the hydrogels to be nontoxic. The hydrogels demonstrated good water-retention behaviour in soil, along with reusability even after 5 cycles. A controlled release profile for urea was evident from the hydrogels wherein macromolecular relaxation played a crucial role in the release mechanism. Growth assays on Abelmoschus esculentus (Okra) plant presented an intuitive evaluation on the growth and water-holding capacity of the CRF hydrogel. The present work demonstrated a facile preparation of CRF hydrogels to enhance the utilization of urea and retain soil humidity as fertilizer carriers.