质子交换膜燃料电池
溶解
材料科学
X射线光电子能谱
催化作用
电流密度
电极
碳纤维
功率密度
密度泛函理论
化学工程
分析化学(期刊)
氧气
化学
物理化学
有机化学
功率(物理)
复合材料
计算化学
工程类
物理
复合数
量子力学
作者
Yanmin Hu,Mengzhao Zhu,Xuan Luo,Geng Wu,Tingting Chao,Yunteng Qu,Fangyao Zhou,Rongbo Sun,Xiao Han,Hai Li,Bin Jiang,Yuen Wu,Xun Hong
标识
DOI:10.1002/anie.202014857
摘要
Abstract Developing highly stable and efficient catalysts toward the oxygen reduction reaction is important for the long‐term operation in proton exchange membrane fuel cells. Reported herein is a facile synthesis of two‐dimensional coplanar Pt‐carbon nanomeshes (NMs) that are composed of highly distorted Pt networks (neck width of 2.05±0.72 nm) and carbon. X‐ray absorption fine structure spectroscopy demonstrated the metallic state of Pt in the coplanar Pt/C NMs. Fuel cell tests verified the excellent activity of the coplanar Pt/C NM catalyst with the peak power density of 1.21 W cm −2 and current density of 0.360 A cm −2 at 0.80 V in the H 2 /O 2 cell. Moreover, the coplanar Pt/C NM electrocatalysts showed superior stability against aggregation, with NM structures preserved intact for a long‐term operation of over 30 000 cycles for electrode measurement, and the working voltage loss was negligible after 120 h in the H 2 /O 2 single cell operation. Density‐functional theory analysis indicates the increased vacancy formation energy of Pt atoms for coplanar Pt/C NMs, restraining the tendency of Pt dissolution and aggregation.
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