磷光
水溶液
光化学
纳米点
纳米颗粒
共价键
量子产额
材料科学
激子
纳米技术
化学
荧光
有机化学
光学
物理
量子力学
作者
Ya‐Chuan Liang,Shanshan Gou,Kai-Kai Liu,Wenjie Wu,Chenzi Guo,Siyu Lu,Jinhao Zang,Xueying Wu,Qing Lou,Lin Dong,Yanfeng Gao,Chongxin Shan
出处
期刊:Nano Today
[Elsevier]
日期:2020-10-01
卷期号:34: 100900-100900
被引量:175
标识
DOI:10.1016/j.nantod.2020.100900
摘要
Water-soluble phosphorescent nanoparticles are highly desirable for biomedical applications. However, the phosphorescence of nanoparticles is usually quenched in aqueous solutions due to the nonradiative deactivation of triplet excitons by the oxygen in water, thus it is a huge challenge to realize water-soluble phosphorescent nanoparticles. Herein, ultralong and efficient phosphorescence has been achieved from water-soluble carbon nanodots (CNDs) by confine CNDs in a nanospace. Silica capsulation layer is used to ensure the solublity of the CNDs, isolate the CNDs from the surrounding oxygen in the aqueous solution. Furthermore, the motion and vibration of covalent bonds in the CNDs are limited. In this way, the nonradiative deactivation rates of triplet excitons has been decreased, and efficient phosphorescence is achieved from water-soluble CNDs. The lifetime and phosphorescence quantum yield of the CNDs are 1.86 s and 11.6 %, both of which are the best values ever reported for water-soluble phosphorescent nanoparticles. In terms of the efficient phosphorescence of the CNDs in aqueous solution, in vivo/vitro afterglow imaging is also been demonstrated.
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