超级电容器
材料科学
循环伏安法
介电谱
化学工程
电化学
扫描电子显微镜
比表面积
多孔性
电流密度
电容
去壳
电极
复合材料
化学
催化作用
有机化学
量子力学
生物
物理
工程类
物理化学
植物
作者
Tian Yongxia,Chengyuan Xiao,Jian Yin,Wenli Zhang,Jinpeng Bao,Haibo Lin,Haiyan Lu
标识
DOI:10.1002/slct.201804002
摘要
Abstract Porous carbon material has been widely used as the electrode material for supercapacitor owing to distinctive advantages of high electrical conductivity, low cost and availability at ease. In this study, rice‐husk‐derived porous carbon (RHPC) is successfully prepared by employing a new activation agent copper chloride (CuCl 2 ). The morphology and porous structure of RHPC are characterized by scanning electron microscope and N 2 adsorption/desorption. The electrochemical performances of RHPC are investigated by alvanostatic charge‐discharge, cyclic voltammetry and electrochemical impedance spectroscopy. The RHPC possesses high porosity and large specific surface area. When used as supercapacitor electrode materials, RHPC exhibits high specific capacitance of 165.23 F⋅g −1 at a current density of 0.5 A⋅g −1 , excellent cycle stability and noticeable high‐rate capacity of 151.69 F⋅g −1 even at a high current density of 20 A⋅g −1 . More importantly, the preparation of this CuCl 2 activator is facile and low‐cost. Besides, the recyclability meet the requirements of environmental concerns.
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