乙烯
吸附
微型多孔材料
吸附
化学
化学工程
材料科学
有机化学
催化作用
工程类
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2018-10-25
卷期号:362 (6413): 415.15-417
标识
DOI:10.1126/science.362.6413.415-o
摘要
Gas Separation Industrial production of ethylene requires its separation from ethane in a cryogenic process that consumes large amounts of energy. An alternative would be differential sorption in microporous materials. Most of these materials bind ethylene more strongly that ethane, but adsorption of ethane would be more efficient. Li et al. found that a metal-organic framework containing iron-peroxo sites bound ethane more strongly than ethylene and could be used to separate the gases at ambient conditions. Science , this issue p. [443][1] [1]: /lookup/doi/10.1126/science.aat0586
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