锌
X射线光电子能谱
氢氧化锌
氢氧化物
腐蚀
氧化物
无机化学
材料科学
降级(电信)
化学
冶金
化学工程
工程类
电信
计算机科学
作者
Jiri Duchoslav,R. Steinberger,M. Arndt,David Stifter
标识
DOI:10.1016/j.corsci.2014.01.037
摘要
A detailed investigation of a potential corrosion product of zinc – zinc hydroxide – using X-ray photoelectron spectroscopy (XPS) was performed to shed light on remarkable inconsistencies in the literature reported reference data, being the key element for the evaluation of the unknown experimental spectra. Our study gives an explanation, showing that zinc hydroxide possesses a highly unstable nature resulting in rapid degradation and leading to the formation of zinc oxide during standard XPS measurements. Furthermore, a probable mechanism of the observed phenomenon, X-ray induced material degradation, is proposed and discussed.
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