A nonpolar/polar composite comprising tungsten sulfide nanosheets on carbon nanofibers (CNFs) is used for the cathode in lithium–sulfur batteries. These batteries demonstrate an ultra-long cycle life of 1500 cycles at a charge/discharge rate of 2 C, and they maintain about 90% specific capacity with a high specific capacity of 502 mA h g−1. These batteries present a significant performance improvement in the field of Li–S batteries. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.