A Solvent‐Polarity‐Induced Interface Self‐Assembly Strategy towards Mesoporous Triazine‐Based Carbon Materials

Triazine-based materials with porous structure have recently received numerous attentions as a fascinating new class because of their superior potential for various applications. However, it is still a formidable challenge to obtain triazine-based materials with precise adjustable meso-scaled pore sizes and controllable pore structures by reported synthesis approaches. Herein, we develop a solvent polarity induced interface self-assembly strategy to construct mesoporous triazine-based carbon materials. In this method, we employ a mixed solvent system within a suitable range of polarity (0.223≤Lippert-Mataga parameter (Δf) ≤0.295) to induce valid self-assembly of skeleton precursor and surfactant. The as-prepared mesoporous triazine-based carbon materials possess uniform tunable pore sizes (8.2-14.0 nm), high surface areas and ultrahigh nitrogen content (up to 18 %). Owing to these intriguing advantages, the fabricated mesoporous triazine-based carbon materials as functionalized porous solid absorbents exhibit predominant CO2 adsorption performance and exceptional selectivity for the capture of CO2 over N2 .