Rational design of MnS nanoparticles anchored on N,S-codoped carbon matrix as anode for lithium-ion batteries

The manganese sulfide (MnS) has attracted more attention as anode material on energy storage and conversion field, owing to its high theoretical capacity (616 ​mA ​h ​g −1 ) and good electrochemical activity. However, low electronic conductivity and large volume expansion during charge-discharge processes have limited its further application. In order to address above mentioned problems, the composites, MnS nanoparticles embedded in N,S-codoped porous carbon skeleton (named as MnS/N,S–C composites), herein have been prepared successfully using metal organic framework (Mn-NTA) as template. The porous carbon skeleton not only can enhance electrode conductivity, but also relieve volume expansion during charge-discharge processes. Thus, the rational design towards electrode architectures has endowed MnS/N,S–C nanocomposites with superior electrochemical performance, which delivers the specific capacities of 676.7 ​mA ​h ​g −1 at the current density of 100 ​mA ​g −1 . • The MnS nanoparticles anchored on N,S-codoped carbon matrix are successfully prepared and display nanorods morphology. • The N, S codoped carbon network could improve electronic conductivity of electrode and prevent nanoparticles agglomeration. • The composites have abundant mesoporous structure, which could shorten transfer path of ion. • The MnS/N,S–C anode displays a good cycling stability with specific capacities of 676.7 ​mA ​h ​g −1 at 100 ​mA ​g −1 .